Rhythm:
e|----------------------------------------------------------------|
B|----------------------------------------------------------------|
G|----------------------------------------------------------------|
D|--6---6/7-7-7/9----9-/11-11-11\9--9-----4-4-----6-6-------------|
A|--7---7/9-9-9/11---11/12-12-12\11-11----6-6-6/7-7-7-------------|
E|--0---0---0-0-0----0-----0--0-----0-----0-0-0---0-0-------------|
Lead:
[ Tab from: https://www.guitartabs.cc/tabs/k/kings_of_leon/arizona_tab_ver_2.html ]
e|----------------------------------------0-0---------------------|
B|--2---4545--/-9----9109109-9-/-12\------5-7bhold----------------|
G|----------------------------------------------------------------|
D|----------------------------------------------------------------|
A|----------------------------------------------------------------|
E|----------------------------------------------------------------|
e|----------------------------------------0--0--------------------|
B|--2---4545--/-9----9109109-9-/-12\------17-19bhold--------------|
G|----------------------------------------------------------------|
D|----------------------------------------------------------------|
A|----------------------------------------------------------------|
E|----------------------------------------------------------------|
Thats pretty much it through the whole song. Listen to the song for the correct timing
For the break after the 'Shake hands', improvise the rhythm into a lead...its not hard.